Firstly, what is a green tariff? It doesn't guarantee that the electricity powering your computer is from a renewable source. However, for at least some of the units you use, the energy company guarantees to put back into the grid an equivalent amount of energy from renewable sources (currently more expensive). You, the customer, pay a little bit more for them to do this, and this increases the market for renewable energy, and supports the building of new renewables capacity.
All power companies have a legal requirement to make 9% of their electricity from renewables, or purchase certificates to make up the difference. Large energy providers seem to have found a handy way of paying for this. Rather than spread the costs among all consumers, those on 'green tariffs' pay more - but without the company actually producing any more renewable energy than it is obliged to anyway.
Small providers are generally a safer bet. The website http://www.greenelectricity.org/ compares various tariffs for the green benefits on offer. From next month there will be a bit more transparency as companies will have to comply with Ofgem guidelines about providing information. The Ofgem rating system has been criticised however. The National Consumer Council did a report which goes into more detail about the issues, but individual tariffs may have changed since it was written in 2006.
One final useful bit of jargon: ROC retiral. This is a Good Thing. ROCs (Renewable Obligation Certificates) are issued to companies producing renewable energy. They can then sell these to other energy company to enable them to meet their legal obligation (see above). Any renewables company that retires some of these certificates rather than selling them makes it harder for other companies not to invest in renewables themselves, and avoids counting the 'greenness' twice.So, is it worth changing? Yes. Switching electricity suppliers isn't a substitute for saving energy, but here are two good reasons to take this action:
1. It's very easy to switch, through http://www.greenelectricity.org/ or another website.
2. It makes you feel good
3. When persistent sales-type people come to your front door trying to persuade you to switch suppliers, you can tell them you're with a green energy company, and they go away. This is a significant bonus in my opinion.